organic chemistry

Know the “normal” state for common organic atoms [3 rules to live by]

Structures of molecules can be difficult to piece together at first when you are just starting in an organic chemistry class. Hopefully you retained some of this knowledge from general chemistry. If not, one of the tricks that can greatly help with this is to know the uncharged or “normal” state for atoms that are […]

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Steps of a Free Radical Reactions [simplified – with a great diagram]

The steps of free radical reactions in 2022 This is one of the best depictions of the steps of free radical reactions I have seen.   It shows what can go on in this reactions and how we get from starting material to desired final product. Radical reactions: a quick overview first. A radical reaction is a

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Resonance between equivalent atoms in organic chemistry means equal bond lengths.

It’s time for resonance in organic chemistry.   Resonance in organic chemistry is one of the most fundamental and useful concepts you will learn in this class. Once most students hear this tip, it makes perfect sense to them, but it isn’t one that you might think of on your own.  Take a look at

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Organic Chemistry: There are only FOUR important IR peaks….that’s IT

Amazingly enough, IR is not used much by professional organic chemists.  This is because all IR can show is different functional groups.  Thus, IR cannot tell the difference between any of the molecules shown below: All of the molecules above will show an OH peak and various C-H stretches, but each spectra will look striking similar. 

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Organic Chemistry Help: Resonance and SN1/SN2

Hi everybody, I wanted to talk briefly today about resonance and sterics and how it can affect and SN1 or SN2.  For background, I hope everyone knows when it comes to SN1 reactions, tertiary substrates are the fastest and primary substrates are the slowest (because of carbocation stability).  Conversely, when it comes to SN2, it

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