{"id":42,"date":"2008-05-22T06:14:26","date_gmt":"2008-05-22T11:14:26","guid":{"rendered":"http:\/\/organicchemistry.wordpress.com\/?p=42"},"modified":"2008-05-22T06:14:26","modified_gmt":"2008-05-22T11:14:26","slug":"organic-chemistry-help-retrosynthesis-on-an-enolate","status":"publish","type":"post","link":"https:\/\/www.aceorganicchem.com\/blog\/organic-chemistry-help-retrosynthesis-on-an-enolate\/","title":{"rendered":"Organic Chemistry Help: Retrosynthesis on an enolate"},"content":{"rendered":"

Hi everybody, one of the questions I hear alot is about enolate product.\u00a0 How do you do the retrosynthetic analysis\u00a0on one?\u00a0 How do you even know it came from an enolate reaction?\u00a0 Here is an example to look at:<\/p>\n

\"\"<\/p>\n

\n
As you can see here,\u00a0a possible\u00a0enolate product is an \u03b1,\u03b2-unsaturated ketone.\u00a0 When you see one of these types of ketones, disconnect first at the double bond and “insert” an oxygen atom, as shown above.\u00a0 Now, it becomes more evident which two carbonyls were participants in the original reaction.<\/div>\n
Remember that in most cases, an\u00a0\u03b1,\u03b2-unsaturated ketone can be derived from an enolate reaction.<\/div>\n
Hopefully this was somewhat helpful.\u00a0 For more information on this and other topics, please visit organic chemistry<\/a>.<\/div>\n
Good luck and happy reacting.<\/div>\n<\/div>\n","protected":false},"excerpt":{"rendered":"

Hi everybody, one of the questions I hear alot is about enolate product.\u00a0 How do you do the retrosynthetic analysis\u00a0on one?\u00a0 How do you even know it came from an enolate reaction?\u00a0 Here is an example to look at: As you can see here,\u00a0a possible\u00a0enolate product is an \u03b1,\u03b2-unsaturated ketone.\u00a0 When you see one of […]<\/p>\n","protected":false},"author":2,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"om_disable_all_campaigns":false,"_monsterinsights_skip_tracking":false,"_monsterinsights_sitenote_active":false,"_monsterinsights_sitenote_note":"","_monsterinsights_sitenote_category":0,"site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"default","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","ast-disable-related-posts":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"default","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center 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