{"id":25,"date":"2022-01-17T12:04:00","date_gmt":"2022-01-17T12:04:00","guid":{"rendered":"http:\/\/organicchemistry.wordpress.com\/2007\/10\/20\/always-sometime-never\/"},"modified":"2022-01-18T21:55:21","modified_gmt":"2022-01-18T21:55:21","slug":"organic-chemistry-rules","status":"publish","type":"post","link":"https:\/\/www.aceorganicchem.com\/blog\/organic-chemistry-rules\/","title":{"rendered":"Organic Chemistry rules: Always, sometime, never."},"content":{"rendered":"\n<h1 class=\"wp-block-heading\" id=\"h-organic-chemistry-rules-never-violate-these\">Organic Chemistry Rules: Never violate these!!<\/h1>\n\n\n\n<p><strong>Disclaimer:<\/strong>&nbsp; This posting applies to&nbsp;Undergraduate&nbsp;organic chemistry.&nbsp; This does NOT apply to crazy physicists who create all&nbsp;sorts of insanity&nbsp;in a laboratory that cannot exist outside a xenon forcefield.<\/p>\n\n\n\n<p><span style=\"line-height: 1.4em;\">In organic chemistry, like in life itself, there are rules. &nbsp;Some of them (known as the &#8220;always\/never&#8221; rules) should never be violated, such as always wash your hands leaving the bathroom, or never spit in church. &nbsp;Other rules (known as the &#8220;sometimes&#8221; rules) are guides that you should be aware of rather than hard rules.&nbsp;<\/span><\/p>\n\n\n\n<p><span style=\"line-height: 1.4em;\">Thus, we present a blog post called &#8220;Organic Chemistry Rules: ALWAYS, Sometimes, NEVER.&#8221;<\/span><\/p>\n\n\n\n<p><strong>ALWAYS\/NEVER:<\/strong><\/p>\n\n\n\n<p>1) Hydrogen ALWAYS has only one bond to it. &nbsp;You will never see an organic molecule that has two bonds to hydrogen.<\/p>\n\n\n\n<p>2) Carbon NEVER has more than four bonds. EVER!<\/p>\n\n\n\n<div class=\"wp-block-image\"><figure class=\"aligncenter size-full\"><a href=\"http:\/\/box5250.temp.domains\/~aceorgan\/blog\/wp-content\/uploads\/2017\/08\/five-bonds-to-carbon.jpg\"><img loading=\"lazy\" decoding=\"async\" width=\"400\" height=\"387\" src=\"https:\/\/www.aceorganicchem.com\/blog\/wp-content\/uploads\/2017\/08\/five-bonds-to-carbon.jpg\" alt=\"organic chemistry rules\" class=\"wp-image-846\" srcset=\"https:\/\/www.aceorganicchem.com\/blog\/wp-content\/uploads\/2017\/08\/five-bonds-to-carbon.jpg 400w, https:\/\/www.aceorganicchem.com\/blog\/wp-content\/uploads\/2017\/08\/five-bonds-to-carbon-300x290.jpg 300w\" sizes=\"auto, (max-width: 400px) 100vw, 400px\" \/><\/a><\/figure><\/div>\n\n\n\n<p>3) Alkaline metals&nbsp;(Li, Na, ect) and alkali earth metals (Be, Mg, Ca, ect) can NEVER be negatively charged. &nbsp;They will always be neutral or positively-charged ions in solution.<\/p>\n\n\n\n<p>4) &nbsp;Noble gases are NEVER a part of any organic molecule. &nbsp;Because they have a full octet, they have very little reason to create a covalent bond.<\/p>\n\n\n\n<p>5) Electrons ALWAYS flow from negative to positive. &nbsp;This is a biggie. &nbsp;And because of this, rule #6 exists.<\/p>\n\n\n\n<p>6) Reaction arrows ALWAYS point from negative to positive. &nbsp;Always point from the nucleophile to the electrophile.<\/p>\n\n\n\n<p><strong>Sometimes:<\/strong><\/p>\n\n\n\n<p>&#8211; Carbon can have 4 bonds (neutral), 3 bonds (positive, negative), or even 2 bonds (carbene)<\/p>\n\n\n\n<p>&#8211; Halogens USUALLY have one bond, but can occasionally have two.<\/p>\n\n\n\n<p>&#8211; Nitrogen usually has 3 bonds (neutral), 4 bonds (positive) or 2 bonds (negative)<\/p>\n\n\n\n<p>&#8211; Oxygen usually has 2 bonds, but can have only 1 bond (negative) or 3 bonds (positive)<\/p>\n\n\n\n<p>&#8211; Phosphorous is USUALLY an oxophile, meaning if it can react with oxygen, it will.<\/p>\n\n\n\n<p>This brings us to another point about knowing the common states of organic atoms. &nbsp;This can really help you in solving organic chemistry if you know the <a href=\"http:\/\/box5250.temp.domains\/~aceorgan\/blog\/know-the-normal-state-for-common-organic-atoms\/\">normal state of organic atoms<\/a> [this is a link to one of our favorite blog posts]<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Organic Chemistry Rules: Never violate these!! Disclaimer:&nbsp; This posting applies to&nbsp;Undergraduate&nbsp;organic chemistry.&nbsp; This does NOT apply to crazy physicists who create all&nbsp;sorts of insanity&nbsp;in a laboratory that cannot exist outside a xenon forcefield. In organic chemistry, like in life itself, there are rules. &nbsp;Some of them (known as the &#8220;always\/never&#8221; rules) should never be violated, [&hellip;]<\/p>\n","protected":false},"author":2,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"om_disable_all_campaigns":false,"_monsterinsights_skip_tracking":false,"_monsterinsights_sitenote_active":false,"_monsterinsights_sitenote_note":"","_monsterinsights_sitenote_category":0,"site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"default","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","ast-disable-related-posts":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"default","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""},"tablet":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""},"mobile":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""}},"ast-content-background-meta":{"desktop":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""},"tablet":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""},"mobile":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""}},"footnotes":""},"categories":[8],"tags":[19],"class_list":["post-25","post","type-post","status-publish","format-standard","hentry","category-o-chem-help","tag-organic-chemistry-help"],"yoast_head":"<!-- This site is optimized with the Yoast SEO plugin v27.3 - https:\/\/yoast.com\/product\/yoast-seo-wordpress\/ -->\n<title>Organic Chemistry rules: Always, sometimes, never [with free book]<\/title>\n<meta name=\"description\" content=\"Organic chemistry rules presented to you through a game called &quot;always, sometimes, never&quot;. You also are given free access to our favorite book in this post\" \/>\n<meta name=\"robots\" content=\"index, follow, max-snippet:-1, max-image-preview:large, max-video-preview:-1\" \/>\n<link rel=\"canonical\" href=\"https:\/\/www.aceorganicchem.com\/blog\/organic-chemistry-rules\/\" \/>\n<meta name=\"twitter:label1\" content=\"Written by\" \/>\n\t<meta name=\"twitter:data1\" content=\"Dr. Michael Pa\" \/>\n\t<meta name=\"twitter:label2\" content=\"Est. reading time\" \/>\n\t<meta name=\"twitter:data2\" content=\"2 minutes\" \/>\n<script type=\"application\/ld+json\" class=\"yoast-schema-graph\">{\"@context\":\"https:\\\/\\\/schema.org\",\"@graph\":[{\"@type\":\"Article\",\"@id\":\"https:\\\/\\\/www.aceorganicchem.com\\\/blog\\\/organic-chemistry-rules\\\/#article\",\"isPartOf\":{\"@id\":\"https:\\\/\\\/www.aceorganicchem.com\\\/blog\\\/organic-chemistry-rules\\\/\"},\"author\":{\"name\":\"Dr. Michael Pa\",\"@id\":\"https:\\\/\\\/www.aceorganicchem.com\\\/blog\\\/#\\\/schema\\\/person\\\/854192b6b8f267c7ee95ddba11dcd4b4\"},\"headline\":\"Organic Chemistry rules: Always, sometime, never.\",\"datePublished\":\"2022-01-17T12:04:00+00:00\",\"dateModified\":\"2022-01-18T21:55:21+00:00\",\"mainEntityOfPage\":{\"@id\":\"https:\\\/\\\/www.aceorganicchem.com\\\/blog\\\/organic-chemistry-rules\\\/\"},\"wordCount\":356,\"commentCount\":0,\"publisher\":{\"@id\":\"https:\\\/\\\/www.aceorganicchem.com\\\/blog\\\/#organization\"},\"image\":{\"@id\":\"https:\\\/\\\/www.aceorganicchem.com\\\/blog\\\/organic-chemistry-rules\\\/#primaryimage\"},\"thumbnailUrl\":\"https:\\\/\\\/www.aceorganicchem.com\\\/blog\\\/wp-content\\\/uploads\\\/2017\\\/08\\\/five-bonds-to-carbon.jpg\",\"keywords\":[\"organic chemistry help\"],\"articleSection\":[\"o-chem help\"],\"inLanguage\":\"en-US\",\"potentialAction\":[{\"@type\":\"CommentAction\",\"name\":\"Comment\",\"target\":[\"https:\\\/\\\/www.aceorganicchem.com\\\/blog\\\/organic-chemistry-rules\\\/#respond\"]}]},{\"@type\":\"WebPage\",\"@id\":\"https:\\\/\\\/www.aceorganicchem.com\\\/blog\\\/organic-chemistry-rules\\\/\",\"url\":\"https:\\\/\\\/www.aceorganicchem.com\\\/blog\\\/organic-chemistry-rules\\\/\",\"name\":\"Organic Chemistry rules: Always, sometimes, never [with free book]\",\"isPartOf\":{\"@id\":\"https:\\\/\\\/www.aceorganicchem.com\\\/blog\\\/#website\"},\"primaryImageOfPage\":{\"@id\":\"https:\\\/\\\/www.aceorganicchem.com\\\/blog\\\/organic-chemistry-rules\\\/#primaryimage\"},\"image\":{\"@id\":\"https:\\\/\\\/www.aceorganicchem.com\\\/blog\\\/organic-chemistry-rules\\\/#primaryimage\"},\"thumbnailUrl\":\"https:\\\/\\\/www.aceorganicchem.com\\\/blog\\\/wp-content\\\/uploads\\\/2017\\\/08\\\/five-bonds-to-carbon.jpg\",\"datePublished\":\"2022-01-17T12:04:00+00:00\",\"dateModified\":\"2022-01-18T21:55:21+00:00\",\"description\":\"Organic chemistry rules presented to you through a game called \\\"always, sometimes, never\\\". 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